ChemInform Abstract: Bio-Inspired Formal Synthesis of Hirsutellones A-C Featuring an Electrophilic Cyclization Triggered by Remote Lewis Acid-Activation

ChemInform Abstract: Bio-Inspired Formal Synthesis of Hirsutellones A-C Featuring an Electrophilic Cyclization Triggered by Remote Lewis Acid-Activation

A bio‐inspired strategy is used to complete the formal synthesis of the antitubercular hirsutellone B (I) and congeners A (II) and C (III), through construction of its decahydrofluorene core from a linear polyene strand activated at both ends by a silyl enol ether and an allyl acetate (not shown).

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Veröffentlicht in:ChemInform 2014-05, Vol.45 (19), p.no-no
Hauptverfasser: Li, Xu-Wen, Ear, Alexandre, Roger, Lukas, Riache, Nassima, Deville, Alexandre, Nay, Bastien
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Sprache:eng
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other bioactive products
ring closure reactions
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container_title ChemInform
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creator Li, Xu-Wen
Ear, Alexandre
Roger, Lukas
Riache, Nassima
Deville, Alexandre
Nay, Bastien
description A bio‐inspired strategy is used to complete the formal synthesis of the antitubercular hirsutellone B (I) and congeners A (II) and C (III), through construction of its decahydrofluorene core from a linear polyene strand activated at both ends by a silyl enol ether and an allyl acetate (not shown).
doi_str_mv 10.1002/chin.201419225
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subjects other bioactive products
ring closure reactions
title ChemInform Abstract: Bio-Inspired Formal Synthesis of Hirsutellones A-C Featuring an Electrophilic Cyclization Triggered by Remote Lewis Acid-Activation
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