ChemInform Abstract: Chiral Iminoesters Derived from D-Glyceraldehyde in [3 + 2] Cycloaddition Reactions. Asymmetric Synthesis of a Key Intermediate in the Synthesis of Neuramidinase Inhibitors

ChemInform Abstract: Chiral Iminoesters Derived from D-Glyceraldehyde in [3 + 2] Cycloaddition Reactions. Asymmetric Synthesis of a Key Intermediate in the Synthesis of Neuramidinase Inhibitors

The title asymmetric [2 + 3] cycloaddition is endo‐selective by using AgOAc as a catalyst and exo‐selective by using CuOAc as a catalyst.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2014-04, Vol.45 (17), p.no-no
Hauptverfasser: Galvez, Jose A., Diaz-de-Villegas, Maria D., Alias, Miriam, Badorrey, Ramon
Format: Artikel
Sprache:eng
Schlagworte:
catalysis
catalysis, phase‐transfer catalysis
cycloaddition reactions
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
phase-transfer catalysis
pyrrole derivatives
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Beschreibung
Zusammenfassung:The title asymmetric [2 + 3] cycloaddition is endo‐selective by using AgOAc as a catalyst and exo‐selective by using CuOAc as a catalyst.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201417118