ChemInform Abstract: p-Nitrophenyl Ethylthioester in Enantioselective Organocatalytic Michael Additions: Different Behavior of [beta]-Aryl and [beta]-Alkyl Enals

ChemInform Abstract: p-Nitrophenyl Ethylthioester in Enantioselective Organocatalytic Michael Additions: Different Behavior of [beta]-Aryl and [beta]-Alkyl Enals

The differences in the reactivity of the thioesters (I) with [beta]-alkyl and [beta]-aryl-substituted enals (II) are overcome by optimization allowing the synthesis of diastereomeric mixtures of Michael adducts (III) and (IV). [PUBLICATION ABSTRACT]

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Veröffentlicht in:ChemInform 2014-04, Vol.45 (13)
Hauptverfasser: Duce, Sara, Jorge, Maria, Alonso, Ines, Garcia Ruano, Jose Luis, Cid, M Belen
Format: Artikel
Sprache:eng
Schlagworte:
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Zusammenfassung:The differences in the reactivity of the thioesters (I) with [beta]-alkyl and [beta]-aryl-substituted enals (II) are overcome by optimization allowing the synthesis of diastereomeric mixtures of Michael adducts (III) and (IV). [PUBLICATION ABSTRACT]
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201413092