ChemInform Abstract: Concise Synthesis of Enantiomerically Pure (1′S,2′R)- and (1′R,2′S)-2S-Amino-3-(2′-aminomethyl-cyclopropyl)propionic Acid: Two E-Diastereoisomers of 4,5-Methano-L-lysine

The zinc‐mediated cyclopropanation of E‐allylic alcohol (II) is the key step in the synthesis of methano‐L‐lysine derivatives (IV) and (V).

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2014-03, Vol.45 (9), p.no-no
Hauptverfasser:	Altamore, Timothy M., Nguyen, Oanh T. K., Churches, Quentin I., Cavanagh, Kate, Nguyen, Xuan T. T., Duggan, Sandhya A. M., Krippner, Guy Y., Duggan, Peter J.
Format:	Artikel
Sprache:	eng
Schlagworte:	amino acids amino acids, peptides diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) peptides ring closure reactions
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Beschreibung
Zusammenfassung:	The zinc‐mediated cyclopropanation of E‐allylic alcohol (II) is the key step in the synthesis of methano‐L‐lysine derivatives (IV) and (V).
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201409203