Highly Regioselective Palladium-catalyzed Double Hydroselenation of Terminal Alkynes with Benzeneselenol in the Presence of Acetic Acid

Highly Regioselective Palladium-catalyzed Double Hydroselenation of Terminal Alkynes with Benzeneselenol in the Presence of Acetic Acid

Palladium diacetate (Pd(OAc)2), in the presence of acetic acid, is found to exhibit excellent catalytic activity for the double hydroselenation of terminal alkynes with benzeneselenol to yield the corresponding diselenoketals regioselectively.

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Veröffentlicht in:Chemistry letters 2013-11, Vol.42 (11), p.1383-1385
Hauptverfasser: Ikeda, Takuma, Tamai, Taichi, Daitou, Masayuki, Minamida, Yoshiaki, Mitamura, Takenori, Kusano, Hiroki, Nomoto, Akihiro, Ogawa, Akiya
Format: Artikel
Sprache:eng
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Zusammenfassung:Palladium diacetate (Pd(OAc)2), in the presence of acetic acid, is found to exhibit excellent catalytic activity for the double hydroselenation of terminal alkynes with benzeneselenol to yield the corresponding diselenoketals regioselectively.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.130641