Investigation of the Pathway for Intramolecular Electron Transfer in Anodic [2 + 2] Cycloaddition Reactions

Investigation of the Pathway for Intramolecular Electron Transfer in Anodic [2 + 2] Cycloaddition Reactions

Intramolecular electron transfer is expected to play a key role in anodic [2 + 2] cycloaddition reactions. We synthesized 2-allyl-6-methoxy-1,2,3,4-tetrahydronaphthalene as an olefin nucleophile to study the [2 + 2] reaction, leading to the finding that the intramolecular electron transfer that comp...

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Veröffentlicht in:Denki kagaku oyobi kōgyō butsuri kagaku 2013/05/05, Vol.81(5), pp.377-379
Hauptverfasser: KAMIMURA, Kazuya, OKADA, Yohei, CHIBA, Kazuhiro
Format: Artikel
Sprache:eng
Schlagworte:
Anodic [2 + 2] Cycloaddition Reaction
Intramolecular Electron Transfer
Olefin Nucleophile
Radical Cation
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Zusammenfassung:Intramolecular electron transfer is expected to play a key role in anodic [2 + 2] cycloaddition reactions. We synthesized 2-allyl-6-methoxy-1,2,3,4-tetrahydronaphthalene as an olefin nucleophile to study the [2 + 2] reaction, leading to the finding that the intramolecular electron transfer that completes the formation of cyclobutane rings occurs mainly through space rather than through bonds.
ISSN:1344-3542
2186-2451
DOI:10.5796/electrochemistry.81.377