Formal anti-Markovnikov Hydroamination of Terminal Aryl Alkynes with Pinacolborane and Hydroxylamines via Zr/Cu Sequential Catalysis

We have developed sequential Zr/Cu catalysis involving regioselective hydroboration and electrophilic amination for the formal anti-Markovnikov hydroamination of terminal aryl alkynes. The reaction system can provide a facile access to enamines from terminal acetylenes with high regioselectivity und...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry letters 2013-10, Vol.42 (10), p.1128-1130
Hauptverfasser:	Sakae, Ryosuke, Hirano, Koji, Satoh, Tetsuya, Miura, Masahiro
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!