Formal anti-Markovnikov Hydroamination of Terminal Aryl Alkynes with Pinacolborane and Hydroxylamines via Zr/Cu Sequential Catalysis

Formal anti-Markovnikov Hydroamination of Terminal Aryl Alkynes with Pinacolborane and Hydroxylamines via Zr/Cu Sequential Catalysis

We have developed sequential Zr/Cu catalysis involving regioselective hydroboration and electrophilic amination for the formal anti-Markovnikov hydroamination of terminal aryl alkynes. The reaction system can provide a facile access to enamines from terminal acetylenes with high regioselectivity und...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2013-10, Vol.42 (10), p.1128-1130
Hauptverfasser: Sakae, Ryosuke, Hirano, Koji, Satoh, Tetsuya, Miura, Masahiro
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 1130
container_issue 10
container_start_page 1128
container_title Chemistry letters
container_volume 42
creator Sakae, Ryosuke
Hirano, Koji
Satoh, Tetsuya
Miura, Masahiro
description We have developed sequential Zr/Cu catalysis involving regioselective hydroboration and electrophilic amination for the formal anti-Markovnikov hydroamination of terminal aryl alkynes. The reaction system can provide a facile access to enamines from terminal acetylenes with high regioselectivity under mild conditions.
doi_str_mv 10.1246/cl.130485
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1478041548</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3184505801</sourcerecordid><originalsourceid>FETCH-LOGICAL-c359t-9eae95832214d55fbdae66038b4726918632364d8b9c60ae632d64f1f40ca3ad3</originalsourceid><addsrcrecordid>eNplkDtPwzAQgC0EEqUw8A8sMTGE-hXXGVHESwKBBCws0cVxhFs3LnYKZOeH4yodkFjOsu-773yH0CklF5QJOdPugnIiVL6HJpQLlZE5zffRhHApszlh7BAdxbgghKiCswn6ufZhBQ5D19vsAcLSf3Y2BXw7NMHDynbQW99h3-IXE7ZXhy_DkIJbDp2J-Mv27_gpvWvvah-gM8nVjOXfg9saEvVpAb-FWbnBz-ZjY1Kz5CmhBzdEG4_RQQsumpPdOUWv11cv5W12_3hzV17eZ5rnRZ8VBkyRK84YFU2et3UDRkrCVS3mTBZUSc64FI2qCy1JynHWSNHSVhANHBo-RWejdx18-kXsq4XfhDRSrKiYKyJoLlSizkdKBx9jMG21DnYFYagoqbZLrrSrxiUnVu7Yd7OyOpm8tqYfFrCG7o_9X-EvS_CDsA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1478041548</pqid></control><display><type>article</type><title>Formal anti-Markovnikov Hydroamination of Terminal Aryl Alkynes with Pinacolborane and Hydroxylamines via Zr/Cu Sequential Catalysis</title><source>Oxford University Press Journals All Titles (1996-Current)</source><creator>Sakae, Ryosuke ; Hirano, Koji ; Satoh, Tetsuya ; Miura, Masahiro</creator><creatorcontrib>Sakae, Ryosuke ; Hirano, Koji ; Satoh, Tetsuya ; Miura, Masahiro</creatorcontrib><description>We have developed sequential Zr/Cu catalysis involving regioselective hydroboration and electrophilic amination for the formal anti-Markovnikov hydroamination of terminal aryl alkynes. The reaction system can provide a facile access to enamines from terminal acetylenes with high regioselectivity under mild conditions.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1246/cl.130485</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><ispartof>Chemistry letters, 2013-10, Vol.42 (10), p.1128-1130</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2013</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-9eae95832214d55fbdae66038b4726918632364d8b9c60ae632d64f1f40ca3ad3</citedby><cites>FETCH-LOGICAL-c359t-9eae95832214d55fbdae66038b4726918632364d8b9c60ae632d64f1f40ca3ad3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Sakae, Ryosuke</creatorcontrib><creatorcontrib>Hirano, Koji</creatorcontrib><creatorcontrib>Satoh, Tetsuya</creatorcontrib><creatorcontrib>Miura, Masahiro</creatorcontrib><title>Formal anti-Markovnikov Hydroamination of Terminal Aryl Alkynes with Pinacolborane and Hydroxylamines via Zr/Cu Sequential Catalysis</title><title>Chemistry letters</title><addtitle>Chemistry Letters</addtitle><description>We have developed sequential Zr/Cu catalysis involving regioselective hydroboration and electrophilic amination for the formal anti-Markovnikov hydroamination of terminal aryl alkynes. The reaction system can provide a facile access to enamines from terminal acetylenes with high regioselectivity under mild conditions.</description><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNplkDtPwzAQgC0EEqUw8A8sMTGE-hXXGVHESwKBBCws0cVxhFs3LnYKZOeH4yodkFjOsu-773yH0CklF5QJOdPugnIiVL6HJpQLlZE5zffRhHApszlh7BAdxbgghKiCswn6ufZhBQ5D19vsAcLSf3Y2BXw7NMHDynbQW99h3-IXE7ZXhy_DkIJbDp2J-Mv27_gpvWvvah-gM8nVjOXfg9saEvVpAb-FWbnBz-ZjY1Kz5CmhBzdEG4_RQQsumpPdOUWv11cv5W12_3hzV17eZ5rnRZ8VBkyRK84YFU2et3UDRkrCVS3mTBZUSc64FI2qCy1JynHWSNHSVhANHBo-RWejdx18-kXsq4XfhDRSrKiYKyJoLlSizkdKBx9jMG21DnYFYagoqbZLrrSrxiUnVu7Yd7OyOpm8tqYfFrCG7o_9X-EvS_CDsA</recordid><startdate>20131005</startdate><enddate>20131005</enddate><creator>Sakae, Ryosuke</creator><creator>Hirano, Koji</creator><creator>Satoh, Tetsuya</creator><creator>Miura, Masahiro</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20131005</creationdate><title>Formal anti-Markovnikov Hydroamination of Terminal Aryl Alkynes with Pinacolborane and Hydroxylamines via Zr/Cu Sequential Catalysis</title><author>Sakae, Ryosuke ; Hirano, Koji ; Satoh, Tetsuya ; Miura, Masahiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-9eae95832214d55fbdae66038b4726918632364d8b9c60ae632d64f1f40ca3ad3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sakae, Ryosuke</creatorcontrib><creatorcontrib>Hirano, Koji</creatorcontrib><creatorcontrib>Satoh, Tetsuya</creatorcontrib><creatorcontrib>Miura, Masahiro</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sakae, Ryosuke</au><au>Hirano, Koji</au><au>Satoh, Tetsuya</au><au>Miura, Masahiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Formal anti-Markovnikov Hydroamination of Terminal Aryl Alkynes with Pinacolborane and Hydroxylamines via Zr/Cu Sequential Catalysis</atitle><jtitle>Chemistry letters</jtitle><addtitle>Chemistry Letters</addtitle><date>2013-10-05</date><risdate>2013</risdate><volume>42</volume><issue>10</issue><spage>1128</spage><epage>1130</epage><pages>1128-1130</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>We have developed sequential Zr/Cu catalysis involving regioselective hydroboration and electrophilic amination for the formal anti-Markovnikov hydroamination of terminal aryl alkynes. The reaction system can provide a facile access to enamines from terminal acetylenes with high regioselectivity under mild conditions.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.130485</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0366-7022
ispartof Chemistry letters, 2013-10, Vol.42 (10), p.1128-1130
issn 0366-7022
1348-0715
language eng
recordid cdi_proquest_journals_1478041548
source Oxford University Press Journals All Titles (1996-Current)
title Formal anti-Markovnikov Hydroamination of Terminal Aryl Alkynes with Pinacolborane and Hydroxylamines via Zr/Cu Sequential Catalysis
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-21T04%3A36%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Formal%20anti-Markovnikov%20Hydroamination%20of%20Terminal%20Aryl%20Alkynes%20with%20Pinacolborane%20and%20Hydroxylamines%20via%20Zr/Cu%20Sequential%20Catalysis&rft.jtitle=Chemistry%20letters&rft.au=Sakae,%20Ryosuke&rft.date=2013-10-05&rft.volume=42&rft.issue=10&rft.spage=1128&rft.epage=1130&rft.pages=1128-1130&rft.issn=0366-7022&rft.eissn=1348-0715&rft_id=info:doi/10.1246/cl.130485&rft_dat=%3Cproquest_cross%3E3184505801%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1478041548&rft_id=info:pmid/&rfr_iscdi=true