Kinetics of Mono- and Dimethoxy-substituted Benzyl Alcohol Oxidation by Phthalimido-N-oxyl Radical

Kinetics of Mono- and Dimethoxy-substituted Benzyl Alcohol Oxidation by Phthalimido-N-oxyl Radical

Kinetics of mono and dimethoxy-substituted benzyl alcohols oxidation by electrogenerated phthalimido-N-oxyl radical were investigated using rotating disk electrode voltammetry. The kinetic data arranged in a Hammett correlation indicated the validity of the peculiar reactivity of veratryl alcohol.

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Veröffentlicht in:Denki kagaku oyobi kōgyō butsuri kagaku 2006/08/05, Vol.74(8), pp.685-687
Hauptverfasser: KISHIOKA, Shin-ya, YAMADA, Akifumi
Format: Artikel
Sprache:eng
Schlagworte:
Benzyl Alcohol
Hammett Rule
N-hydroxyphthalimide
Nitroxyl Radical
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Beschreibung
Zusammenfassung:Kinetics of mono and dimethoxy-substituted benzyl alcohols oxidation by electrogenerated phthalimido-N-oxyl radical were investigated using rotating disk electrode voltammetry. The kinetic data arranged in a Hammett correlation indicated the validity of the peculiar reactivity of veratryl alcohol.
ISSN:1344-3542
2186-2451
DOI:10.5796/electrochemistry.74.685