Oxidative esterification of renewable furfural on gold-based catalysts: Which is the best support?
•Gold-based catalysts were investigated in the oxidative esterification of furfural.•Catalytic performances follow the trend: Au/ZrO2>Au/CeO2≫Au/TiO2.•High Au dispersion and specific surface area are essential for good conversion.•Suitable acid–base properties of the support are important for goo...
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Veröffentlicht in: | Journal of catalysis 2014-01, Vol.309, p.241-247 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | •Gold-based catalysts were investigated in the oxidative esterification of furfural.•Catalytic performances follow the trend: Au/ZrO2>Au/CeO2≫Au/TiO2.•High Au dispersion and specific surface area are essential for good conversion.•Suitable acid–base properties of the support are important for good selectivity.•Au/ZrO2 fulfills the compromise and proved to be active, selective, recyclable.
Gold-based catalysts over different supports were investigated in the oxidative esterification of furfural by employing an efficient and sustainable process. The catalytic performances follow the trend: Zirconia–Au>Ceria–Au≫Titania–Au. Zirconia came out to be the best support option to promote activity, selectivity and also stability. The chemical and morphological properties observed for zirconia-supported sample seem to fulfill a good compromise between high gold dispersion and the presence of suitable acid–base properties, for good selectivity. Moreover, stability and recycling of the catalysts were also investigated. |
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ISSN: | 0021-9517 1090-2694 |
DOI: | 10.1016/j.jcat.2013.10.005 |