ChemInform Abstract: A Survey of Sulfide Ligands for Allylic C-H Oxidations of Terminal Olefins

Screening a 37‐membered library of thioether ligands has shown that tetrahydrothiophene is a highly reactive and selective ligand for Pd‐catalyzed allylic C—H oxidation reactions.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2014-01, Vol.45 (2), p.no-no
Hauptverfasser:	Le, Chi, Kunchithapatham, Kamala, Henderson, William H., Check, Christopher T., Stambuli, James P.
Format:	Artikel
Sprache:	eng
Schlagworte:	alkenes (acyclic compounds) alkenes (benzene compounds) catalysis catalysis, phase‐transfer catalysis dehydrogenation e/z-selectivity (incl. e/z-isomerism) Ligands oxidation oxidation, dehydrogenation phase-transfer catalysis
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Beschreibung
Zusammenfassung:	Screening a 37‐membered library of thioether ligands has shown that tetrahydrothiophene is a highly reactive and selective ligand for Pd‐catalyzed allylic C—H oxidation reactions.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201402026