Copper-free Sonogashira Coupling Reaction in Phosphonium Amino Acid Ionic Liquids

Phosphonium amino acid ionic liquids were found to be useful for the copper-free and amine-free Sonogashira coupling reaction. A hydrophobic and lipophobic ionic liquid permitted easy separation of the product from ionic liquid and catalyst, and the recovered ionic liquid containing Pd catalyst coul...

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Veröffentlicht in:Chemistry letters 2011-09, Vol.40 (9), p.1027-1029
Hauptverfasser: Fukuyama, Takahide, Rahman, Md. Taifur, Maetani, Shinji, Ryu, Ilhyong
Format: Artikel
Sprache:eng
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Zusammenfassung:Phosphonium amino acid ionic liquids were found to be useful for the copper-free and amine-free Sonogashira coupling reaction. A hydrophobic and lipophobic ionic liquid permitted easy separation of the product from ionic liquid and catalyst, and the recovered ionic liquid containing Pd catalyst could be reused.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2011.1027