Remote Controlled Intramolecular Exciplex Formation and Enhanced Photoisomerization in Stilbene-cored Poly(benzyl ether) Dendrimers with Alkoxycarbonyl Surface Functional Groups

Exciplex-induced isomerization played a key role in highly efficient photoisomerization of stilbene-cored poly(benzyl ether) dendrimers tethering two alkoxycarbonyl surface functional groups at the meta position of each terminating phenyl group. This is the first report on the control of photochemic...

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Veröffentlicht in:Chemistry letters 2011-10, Vol.40 (10), p.1124-1126
Hauptverfasser: Takizawa, Tsutomu, Arai, Tatsuo
Format: Artikel
Sprache:eng
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Zusammenfassung:Exciplex-induced isomerization played a key role in highly efficient photoisomerization of stilbene-cored poly(benzyl ether) dendrimers tethering two alkoxycarbonyl surface functional groups at the meta position of each terminating phenyl group. This is the first report on the control of photochemical behavior of dendrimers using intramolecular exciplex formation.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2011.1124