Photocatalytic Styrene Polymerization by Novel Bichromophoric Pd Catalyst Having Long Excited-state Lifetime
The reaction of the novel bichromophoric Pd complexes with styrene resulted in the formation of polymer or dimer by UV–vis light irradiation, depending upon the connectivity of the naphthyl moiety. The Pd complex having the bichromophore with a Ru(II)–polypyridyl and a naphthyl moiety connected by a...
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| Veröffentlicht in: | Chemistry letters 2010-09, Vol.39 (9), p.915-917 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The reaction of the novel bichromophoric Pd complexes with styrene resulted in the formation of polymer or dimer by UV–vis light irradiation, depending upon the connectivity of the naphthyl moiety. The Pd complex having the bichromophore with a Ru(II)–polypyridyl and a naphthyl moiety connected by a single σ bond contained long-lived 3MLCT emitting species. |
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| ISSN: | 0366-7022 1348-0715 |
| DOI: | 10.1246/cl.2010.915 |