One Component Membrane Reactor for Partial Oxidation of Methane Using Asymmetric Membranes

Oxygen permeable asymmetric membranes of Ca0.8Sr0.2Ti0.7Fe0.3O3−δ were applied to a one-component membrane reactor (OCMR) for the partial oxidation of methane. CH4 conversion and oxygen flux of OCMR with a 43-μm dense layer at 1173 K reached 71% and 1.7 mL min−1 cm−2, respectively. These values are...

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Veröffentlicht in:Chemistry letters 2009-05, Vol.38 (5), p.452-453
Hauptverfasser: Araki, Sadao, Hoshi, Yasushi, Hamakawa, Satoshi, Hikazudani, Susumu, Mizukami, Fujio
Format: Artikel
Sprache:eng
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Zusammenfassung:Oxygen permeable asymmetric membranes of Ca0.8Sr0.2Ti0.7Fe0.3O3−δ were applied to a one-component membrane reactor (OCMR) for the partial oxidation of methane. CH4 conversion and oxygen flux of OCMR with a 43-μm dense layer at 1173 K reached 71% and 1.7 mL min−1 cm−2, respectively. These values are 2.5 times greater than that of a 500-μm self-supported membrane.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2009.452