Promoting Effect of Re Addition to Rh/SiO2 on Glycerol Hydrogenolysis

Modification of Rh/SiO2 with ReOx enhanced the activity of glycerol hydrogenolysis remarkably and suppressed degradation reactions simultaneously. At the same time, the formation of 1,3-propanediol became more favorable on the Rh–ReOx/SiO2.

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Veröffentlicht in:Chemistry letters 2009-06, Vol.38 (6), p.540-541
Hauptverfasser: Shimao, Akira, Koso, Shuichi, Ueda, Naoyuki, Shinmi, Yasunori, Furikado, Ippei, Tomishige, Keiichi
Format: Artikel
Sprache:eng
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Zusammenfassung:Modification of Rh/SiO2 with ReOx enhanced the activity of glycerol hydrogenolysis remarkably and suppressed degradation reactions simultaneously. At the same time, the formation of 1,3-propanediol became more favorable on the Rh–ReOx/SiO2.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2009.540