Metal–Metal Bond Formed in Tetrakis(2-pyridonato)Copper(II)–Platinum(II)/Palladium(II) Complexes

Metal–Metal Bond Formed in Tetrakis(2-pyridonato)Copper(II)–Platinum(II)/Palladium(II) Complexes

New tetrakis(2-pyridonato)copper(II)–palladium(II)/platinum(II) complexes, [CuPd(2-pyrd)4(py)] (1), [CuPt(2-pyrd)4(py)] (2), [CuPd(2-pyrd)4(H2O)] (3), and [CuPt(2-pyrd)4(H2O)] (4) (2-pyrd = 2-pyridone, py = pyridine), were prepared, and the metal–metal bonds between PtII/PdII and CuII atoms were evi...

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Veröffentlicht in:Chemistry letters 2008-12, Vol.37 (12), p.1220-1221
Hauptverfasser: Ichieda, Naoko, Kamimura, Tetsuya, Wasada-Tsutsui, Yuko, Funahashi, Yasuhiro, Ozawa, Tomohiro, Jitsukawa, Koichiro, Masuda, Hideki
Format: Artikel
Sprache:eng
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Zusammenfassung:New tetrakis(2-pyridonato)copper(II)–palladium(II)/platinum(II) complexes, [CuPd(2-pyrd)4(py)] (1), [CuPt(2-pyrd)4(py)] (2), [CuPd(2-pyrd)4(H2O)] (3), and [CuPt(2-pyrd)4(H2O)] (4) (2-pyrd = 2-pyridone, py = pyridine), were prepared, and the metal–metal bonds between PtII/PdII and CuII atoms were evidenced on the basis of X-ray structural and ESR spectroscopic methods, which were also supported from the DFT calculations.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2008.1220