Synthesis and Chiral Recognition of Novel Regioselectively Substituted Amylose Derivatives

Synthesis and Chiral Recognition of Novel Regioselectively Substituted Amylose Derivatives

Two novel amylose derivatives 1a and 1b bearing different substituents at 2-, 3-, and 6-positions of a glucose ring have been successfully synthesized, and their abilities of enantiomer resolution in high-performance liquid chromatography (HPLC) have been evaluated. These derivatives exhibited the a...

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Veröffentlicht in:Chemistry letters 2008-05, Vol.37 (5), p.558-559
Hauptverfasser: Kondo, Shunsuke, Yamamoto, Chiyo, Kamigaito, Masami, Okamoto, Yoshio
Format: Artikel
Sprache:eng
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Zusammenfassung:Two novel amylose derivatives 1a and 1b bearing different substituents at 2-, 3-, and 6-positions of a glucose ring have been successfully synthesized, and their abilities of enantiomer resolution in high-performance liquid chromatography (HPLC) have been evaluated. These derivatives exhibited the ability comparable or better to the commercial amylose-based column, Chiralpak AD.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2008.558