Efficient Formation of Homo and Hetero Metal Clusters by Triangular Trisaloph Ligand as a Partial Template

Efficient Formation of Homo and Hetero Metal Clusters by Triangular Trisaloph Ligand as a Partial Template

Homo metal cluster containing seven Zn atoms was efficiently synthesized in high yield via a template effect of a trisaloph ligand and characterized by NMR, MS, X-ray crystallography, etc. The homo cluster can be converted quantitatively to Zn3·La hetero metal cluster.

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Veröffentlicht in:Chemistry letters 2006-09, Vol.35 (9), p.1070-1071
Hauptverfasser: Nabeshima, Tatsuya, Miyazaki, Hayato, Iwasaki, Atsushi, Akine, Shigehisa, Saiki, Toshiyuki, Ikeda, Chusaku, Sato, Soichi
Format: Artikel
Sprache:eng
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Zusammenfassung:Homo metal cluster containing seven Zn atoms was efficiently synthesized in high yield via a template effect of a trisaloph ligand and characterized by NMR, MS, X-ray crystallography, etc. The homo cluster can be converted quantitatively to Zn3·La hetero metal cluster.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2006.1070