Reaction of Allylic-type Diindium Compounds with Electrophiles

Reaction of Allylic-type Diindium Compounds with Electrophiles

Allylic-type diindium reagents were prepared from 3-bromo-1-iodopropene (1a), 3-bromo-1-iodo-1-phenylpropene (1b), or 2,4-diiodobut-2-en-1-ol (1c) with metallic indium, and their successive coupling with electrophiles was examined. The coupling behavior of the diindium reagents was found to depend o...

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Veröffentlicht in:Chemistry letters 2006-03, Vol.35 (3), p.314-315
Hauptverfasser: Hirashita, Tsunehisa, Arai, Shun, Mitsui, Kazuma, Makino, Hajime, Araki, Shuki
Format: Artikel
Sprache:eng
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Zusammenfassung:Allylic-type diindium reagents were prepared from 3-bromo-1-iodopropene (1a), 3-bromo-1-iodo-1-phenylpropene (1b), or 2,4-diiodobut-2-en-1-ol (1c) with metallic indium, and their successive coupling with electrophiles was examined. The coupling behavior of the diindium reagents was found to depend on the electrophiles and the substituent on the diindium compounds.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2006.314