Laser-flash Photolysis of DMSO–Cl Complexes in Dimethyl Sulfoxide/CCl4 Mixed Solvent
DMSO–Cl complexes were produced by pulse radiolysis of mixtures of dimethyl sulfoxide (DMSO) and CCl4 of various compositions, and photochemical reactions were studied by laser flash photolysis. The quantum yields of intramolecular hydrogen abstraction depend strongly on both solvent composition and...
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| Veröffentlicht in: | Chemistry letters 2005-06, Vol.34 (6), p.794-795 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | DMSO–Cl complexes were produced by pulse radiolysis of mixtures of dimethyl sulfoxide (DMSO) and CCl4 of various compositions, and photochemical reactions were studied by laser flash photolysis. The quantum yields of intramolecular hydrogen abstraction depend strongly on both solvent composition and additives. |
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| ISSN: | 0366-7022 1348-0715 |
| DOI: | 10.1246/cl.2005.794 |