Transformation of Double Hydrogen-bonding Motifs of TTF–Uracil System by Redox Change

Transformation of Double Hydrogen-bonding Motifs of TTF–Uracil System by Redox Change

A TTF derivative with an N1-tert-butyluracil moiety, TtbU, was prepared as a new electron-donor molecule capable of multiple hydrogen-bondings. Formation of the two different types of double hydrogen-bonding motifs, Watson–Crick and reverse Watson–Crick types, was demonstrated for the first time bet...

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Veröffentlicht in:Chemistry letters 2005-10, Vol.34 (10), p.1326-1327
Hauptverfasser: Miyazaki, Eigo, Morita, Yasushi, Umemoto, Yoshikazu, Fukui, Kozo, Nakasuji, Kazuhiro
Format: Artikel
Sprache:eng
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Zusammenfassung:A TTF derivative with an N1-tert-butyluracil moiety, TtbU, was prepared as a new electron-donor molecule capable of multiple hydrogen-bondings. Formation of the two different types of double hydrogen-bonding motifs, Watson–Crick and reverse Watson–Crick types, was demonstrated for the first time between TtbU and its I3− salt in the crystalline states.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2005.1326