Molecular Design and Crystal Structures of Chiral Macrotricyclic Cage Amines

Molecular Design and Crystal Structures of Chiral Macrotricyclic Cage Amines

Chiral macrotricyclic cage amines have been synthesized; their X-ray structures have revealed that the asymmetric framework has been formed by adding a single chiral carbon into methylene skeleton of cage amine. The 1H NMR spectra have shown the stable and rigid conformation in solution.

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Veröffentlicht in:Chemistry letters 2004-09, Vol.33 (9), p.1100-1101
Hauptverfasser: Yoshida, Haruki, Izumi, Mitsunori, Ito, Naohito, Ichikawa, Kazuhiko, Shiro, Motoo
Format: Artikel
Sprache:eng
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Zusammenfassung:Chiral macrotricyclic cage amines have been synthesized; their X-ray structures have revealed that the asymmetric framework has been formed by adding a single chiral carbon into methylene skeleton of cage amine. The 1H NMR spectra have shown the stable and rigid conformation in solution.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2004.1100