Polarity of Room-Temperature Ionic Liquid as Examined by EPR Spectroscopy

Polarity of several ionic liquids was examined by 14N hyperfine coupling constant of nitroxide radical measured by EPR method. Polarity judged from EPR agrees well with those by solvatochromic dyes, suggesting that EPR is another valuable probe for polarity of ionic liquids.

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Veröffentlicht in:Chemistry letters 2004-11, Vol.33 (11), p.1464-1465
Hauptverfasser: Kawai, Akio, Hidemori, Takehiro, Shibuya, Kazuhiko
Format: Artikel
Sprache:eng
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Zusammenfassung:Polarity of several ionic liquids was examined by 14N hyperfine coupling constant of nitroxide radical measured by EPR method. Polarity judged from EPR agrees well with those by solvatochromic dyes, suggesting that EPR is another valuable probe for polarity of ionic liquids.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2004.1464