Single-crystal-to-Single-crystal Polymerization of 4,4′-Butadiynedibenzylammonium Disorbate

Single-crystal-to-Single-crystal Polymerization of 4,4′-Butadiynedibenzylammonium Disorbate

Solid-state polymerization of 4,4′-butadiynedibenzylammonium disorbate was investigated. The quantitative polymer yield of the diene moieties was achieved under UV-, X-ray, and γ-ray irradiation, whereas the conversion of diyne moieties was low. X-ray crystal structure analyses of monomer and polyme...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2004-10, Vol.33 (10), p.1312-1313
Hauptverfasser: Odani, Toru, Okada, Shuji, Kabuto, Chizuko, Kimura, Tatsumi, Matsuda, Hiro, Matsumoto, Akikazu, Nakanishi, Hachiro
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Solid-state polymerization of 4,4′-butadiynedibenzylammonium disorbate was investigated. The quantitative polymer yield of the diene moieties was achieved under UV-, X-ray, and γ-ray irradiation, whereas the conversion of diyne moieties was low. X-ray crystal structure analyses of monomer and polymer crystals show the polymerization proceeded under topochemical polymerization mechanism indeed.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2004.1312