Bicyclo[10.10.10]dotriacontanes
Bicyclo[10.10.10]dotriacontanes, the largest bicyclo[n.n.n]alkanes ever known, have been first synthesized by Raney nickel reduction of trithienylmethanophanes consisiting of two tris(2-thienyl)methanes and three etheno bridges. X-ray crystallographic analysis of a crystalline derivative confirmed t...
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| Veröffentlicht in: | Chemistry letters 2004-08, Vol.33 (8), p.1018 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Bicyclo[10.10.10]dotriacontanes, the largest bicyclo[n.n.n]alkanes ever known, have been first synthesized by Raney nickel reduction of trithienylmethanophanes consisiting of two tris(2-thienyl)methanes and three etheno bridges. X-ray crystallographic analysis of a crystalline derivative confirmed the structure, though disorder of included hexane molecules lowered the accuracy. |
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| ISSN: | 0366-7022 1348-0715 |