The First Luminescent Anionic Bis(ethynylphenanthroline)gold(I) Complex

The First Luminescent Anionic Bis(ethynylphenanthroline)gold(I) Complex

First anionic bis(ethynylphenanthroline)gold(I) complex and neutral diethynylphenanthroline–digold(I) complex have demonstrated an intense phosphorescence which is assignable to 3π–π*(C≡C) emission even at room temperature. It is appropriate to highlight the role of gold(I) coordination which enable...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2004-03, Vol.33 (3), p.210-211
Hauptverfasser: Yamamoto, Youhei, Shiotsuka, Michito, Okuno, Sigeru, Onaka, Satoru
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:First anionic bis(ethynylphenanthroline)gold(I) complex and neutral diethynylphenanthroline–digold(I) complex have demonstrated an intense phosphorescence which is assignable to 3π–π*(C≡C) emission even at room temperature. It is appropriate to highlight the role of gold(I) coordination which enables the spin–orbit coupling and facilitates the observation of triplet emissions.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2004.210