Aromatic Iodine-Assisted Self-assembly of a Cobalt(II) Complex of Ferron (Ferron = 7-iodo-8-hydroxyquinoline-5-sulfonate)

Aromatic Iodine-Assisted Self-assembly of a Cobalt(II) Complex of Ferron (Ferron = 7-iodo-8-hydroxyquinoline-5-sulfonate)

A dimeric Co(II) complex of ferron (=7-iodo-8-hydroxyquinoline-5-sulfonate) was isolated as crystals and structurally characterized. Weak I···H and I···C interactions involving the iodoquinoline rings and complementary steric requirements for I···I contacts led to self-assembly of the complex, which...

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Veröffentlicht in:Chemistry letters 2004-05, Vol.33 (5), p.556-557
Hauptverfasser: Zhang, Feng, Li, Yi-Zhi, Gao, Xu, Chen, Hui-Lan, Liu, Qi-Tao, Odani, Akira, Yamauchi, Osamu
Format: Artikel
Sprache:eng
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Zusammenfassung:A dimeric Co(II) complex of ferron (=7-iodo-8-hydroxyquinoline-5-sulfonate) was isolated as crystals and structurally characterized. Weak I···H and I···C interactions involving the iodoquinoline rings and complementary steric requirements for I···I contacts led to self-assembly of the complex, which indicates versatile nature of the iodine atom in intermolecular interactions.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2004.556