Unprecedented Soliton Formation Mechanism in Quasi-One-Dimensional Chloro-Bridged PtII- PtIV Mixed-Valence Compound, {[Pt(en)2][PtCl2(en)2]}3(CuCl4)4·12H2O

Unprecedented Soliton Formation Mechanism in Quasi-One-Dimensional Chloro-Bridged PtII- PtIV Mixed-Valence Compound, {[Pt(en)2][PtCl2(en)2]}3(CuCl4)4·12H2O

A new type of complex consisting of double liner-chain structure {[Pt(en)2][PtCl2(en)2]}3(CuCl4)4·12H2O was synthesized. High concentration (ca. 200 times larger than the literature) of neutral soliton (PtIII component) formation was found. This unprecedented soliton formation mechanism will be disc...

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Veröffentlicht in:Chemistry letters 2003-03, Vol.32 (3), p.278-279
Hauptverfasser: Yamashita, Masahiro, Aso, Hidemitsu, Matsunaga, Satoshi, Takizawa, Koichi, Nakata, Kazuya, Kachi-Terajima, Chihiro, Iwahori, Fumiyasu, Ishii, Tomohiko, Miyasaka, Hitoshi, Sugiura, Ken-ichi, Kawashima, Takuya, Takai, Kenzi, Kuroda, Noritaka, Shiro, Motoo, Kishida, Hideo, Okamoto, Hiroshi, Takahashi, Hiroyuki, Tanaka, Hisaaki, Marumoto, Kazuhiro, Kuroda, Shin-ichi
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Sprache:eng
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Zusammenfassung:A new type of complex consisting of double liner-chain structure {[Pt(en)2][PtCl2(en)2]}3(CuCl4)4·12H2O was synthesized. High concentration (ca. 200 times larger than the literature) of neutral soliton (PtIII component) formation was found. This unprecedented soliton formation mechanism will be discussed.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2003.278