Selective Reduction of [alpha]-Chloroketone to [alpha]-Chloroalcohol Using Hydrogen Transfer from Alcohol over Metal Oxide Catalysts

Selective Reduction of [alpha]-Chloroketone to [alpha]-Chloroalcohol Using Hydrogen Transfer from Alcohol over Metal Oxide Catalysts

The carbonyl group of 1,3-dichloro-2-propanone was reduced selectively through hydrogen transfer from 2-butanol over MgO, SiO2·Al2O3, Al2O3, and ZrO2. It is suggested that the reaction is promoted by either base or acid site of the catalysts.

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Veröffentlicht in:Chemistry letters 2003-12, Vol.32 (12), p.1132
Hauptverfasser: Gotoh, Kunihiro, Kubo, Jun, Ueda, Wataru, Mori, Tohru, Morikawa, Yutaka
Format: Artikel
Sprache:eng
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Zusammenfassung:The carbonyl group of 1,3-dichloro-2-propanone was reduced selectively through hydrogen transfer from 2-butanol over MgO, SiO2·Al2O3, Al2O3, and ZrO2. It is suggested that the reaction is promoted by either base or acid site of the catalysts.
ISSN:0366-7022
1348-0715