Polymer and “Trimer-of-Dimers” Complexes Derived from [Rh2(form)4] (form− = N,N′-Di-p-tolylformamidinate anion) and 1,4-Diisocyanobenzene

Polymer and “Trimer-of-Dimers” Complexes Derived from [Rh2(form)4] (form− = N,N′-Di-p-tolylformamidinate anion) and 1,4-Diisocyanobenzene

A polymer complex ([Rh2(form)4(1,4-dib)]n; form− = N,N′-di-p-tolylformamidinate anion, 1,4-dib = 1,4-diisocyanobenzene) and a “trimer-of-dimers” complex ([{Rh2(form)4}3(1,4-dib)2]) were prepared. They were characterized based on the elemental analyses, X-ray structure analyses, and diffuse reflectan...

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Veröffentlicht in:Chemistry letters 2003-10, Vol.32 (10), p.946-947
Hauptverfasser: Handa, Makoto, Yasuda, Motoi, Muraki, Yasuhiro, Yoshioka, Daisuke, Mikuriya, Masahiro, Kasuga, Kuninobu
Format: Artikel
Sprache:eng
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Zusammenfassung:A polymer complex ([Rh2(form)4(1,4-dib)]n; form− = N,N′-di-p-tolylformamidinate anion, 1,4-dib = 1,4-diisocyanobenzene) and a “trimer-of-dimers” complex ([{Rh2(form)4}3(1,4-dib)2]) were prepared. They were characterized based on the elemental analyses, X-ray structure analyses, and diffuse reflectance spectra.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2003.946