Ruthenium Oxyl Radical Complex Containing o-Quinone Ligand Detected by ESR Measurements of Spin Trapping Technique

Ruthenium Oxyl Radical Complex Containing o-Quinone Ligand Detected by ESR Measurements of Spin Trapping Technique

Ruthenium-quinone complex containing an aqua ligand, [RuII(trpy)(35tBu2Q)(OH2)](ClO4)2 (trpy=2,2′:6′,2″-terpyridine, 35tBu2Q=3,5-di-tert-butyl-1,2-benzoquinone) underwent deprotonation of an aqua ligand accompanied with intramolecular electron transfer from O2− ligand to quinone ligand generating O•...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2002-08, Vol.31 (8), p.868-869
Hauptverfasser: Kobayashi, Katsuaki, Ohtsu, Hideki, Wada, Tohru, Tanaka, Koji
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Ruthenium-quinone complex containing an aqua ligand, [RuII(trpy)(35tBu2Q)(OH2)](ClO4)2 (trpy=2,2′:6′,2″-terpyridine, 35tBu2Q=3,5-di-tert-butyl-1,2-benzoquinone) underwent deprotonation of an aqua ligand accompanied with intramolecular electron transfer from O2− ligand to quinone ligand generating O•− ligand.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2002.868