Synthesis and Application of [Mo8O16Cl2(OCH3)6(HOCH3)4] to Magnetoresistant Oxides
An octanuclear oxomolybdenum(V) cluster compound [Mo8O16Cl2(OCH3)6(HOCH3)4] was prepared from the reaction of oxomolybdenum(V) chloride and the potassium salt of triethanolamine in methanol. The complex was used to prepare Sr2FeMoO6, which shows a very high negative magnetoresistance of 33% with a m...
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| Veröffentlicht in: | Chemistry letters 2002-07, Vol.31 (7), p.650-651 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | An octanuclear oxomolybdenum(V) cluster compound [Mo8O16Cl2(OCH3)6(HOCH3)4] was prepared from the reaction of oxomolybdenum(V) chloride and the potassium salt of triethanolamine in methanol. The complex was used to prepare Sr2FeMoO6, which shows a very high negative magnetoresistance of 33% with a magnetic field of 0.8 T at 12 K. |
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| ISSN: | 0366-7022 1348-0715 |
| DOI: | 10.1246/cl.2002.650 |