Tertiary Amine-Accelerated Allylgallation of Terminal Alkynes
Allylic gallium sesquibromides prepared by reduction of allylic bromides with gallium metal in the presence of a catalytic amount of indium, add to terminal alkynes with the aid of a tertiary amine to give 1,4-dienes.
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| Veröffentlicht in: | Chemistry letters 2002-02, Vol.31 (2), p.172-173 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Allylic gallium sesquibromides prepared by reduction of allylic bromides with gallium metal in the presence of a catalytic amount of indium, add to terminal alkynes with the aid of a tertiary amine to give 1,4-dienes. |
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| ISSN: | 0366-7022 1348-0715 |
| DOI: | 10.1246/cl.2002.172 |