Asymmetric Cyclization via Oxygen Cation Radical

Aerobic oxidative cyclization of 2,2'-dihydroxystilbenes via oxygen cation radical to give cis-4b,9b-dihydrobenzofuro[3,2-b]benzofurans was carried out in an enantioselective manner (up to 89% ee) by using (nitrosyl)Ru(salen) 10 as the catalyst under photo-irradiated conditions.

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Veröffentlicht in:Chemistry letters 2002-01, Vol.31 (1), p.36
Hauptverfasser: Masutani, Kouta, Irie, Ryo, Katsuki, Tsutomu
Format: Artikel
Sprache:eng
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Zusammenfassung:Aerobic oxidative cyclization of 2,2'-dihydroxystilbenes via oxygen cation radical to give cis-4b,9b-dihydrobenzofuro[3,2-b]benzofurans was carried out in an enantioselective manner (up to 89% ee) by using (nitrosyl)Ru(salen) 10 as the catalyst under photo-irradiated conditions.
ISSN:0366-7022
1348-0715