Wavelength Dependent Regioselective E(trans)→Z(cis) Photoisomerization in Anthryldienes

Wavelength Dependent Regioselective E(trans)→Z(cis) Photoisomerization in Anthryldienes

Anthryldiene derivatives carrying electron withdrawing end group displayed wavelength dependant regio selective E(trans) → Z(cis) isomerization from the singlet excited state. Fluorescence studies indicated the highly polarized/charge-transfer nature of the singlet excited state.

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Veröffentlicht in:Chemistry letters 2001-03, Vol.30 (3), p.186-187
Hauptverfasser: Reddy, M. Janaki Ram, Rao, G. Venugopal, Bushan, K. Mani, Reddy, Maruthi Janaki Ram, Gopal, V. Raj, Rao, V. Jayathirtha
Format: Artikel
Sprache:eng
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Zusammenfassung:Anthryldiene derivatives carrying electron withdrawing end group displayed wavelength dependant regio selective E(trans) → Z(cis) isomerization from the singlet excited state. Fluorescence studies indicated the highly polarized/charge-transfer nature of the singlet excited state.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2001.186