Functional Flavin Receptors. Bis-melamine Derivatives Bearing a Guanidinium Ion Which Bind 6-Azaflavin and a Thymine-Linked Substrate through Hydrogen Bonds in Chloroform

Bis-melamine derivatives bearing a guanidinium ion bind 6-azaflavin via five hydrogen bonds and an NADH model having a thymine moiety via three H-bonds in CHCl3, resulting in the rate acceleration due to the proximity effect.

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Veröffentlicht in:Chemistry letters 2000-09, Vol.29 (9), p.1018-1019
Hauptverfasser: Hayashi, Tomohiro, Fujimoto, Akihide, Kajiki, Takeshi, Kondo, Shin-ichi, Yano, Yumihiko
Format: Artikel
Sprache:eng
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Zusammenfassung:Bis-melamine derivatives bearing a guanidinium ion bind 6-azaflavin via five hydrogen bonds and an NADH model having a thymine moiety via three H-bonds in CHCl3, resulting in the rate acceleration due to the proximity effect.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2000.1018