Coordination of Epithio Groups of p-tert-Butylthiacalix[4]arene in a Zn2+ Complex Studied by X-Ray Crystallography

Single-crystal X-ray analysis has shown that p-tert-butylthiacalix[4]arene (H4L) binds to Zn2+ ion by bridging sulfur atoms in addition to phenolic oxygen atoms to form [Zn4L(H2L)2].

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Veröffentlicht in:Chemistry letters 1999-03, Vol.28 (3), p.219-220
Hauptverfasser: Iki, Nobuhiko, Morohashi, Naoya, Kabuto, Chizuko, Miyano, Sotaro
Format: Artikel
Sprache:eng
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Zusammenfassung:Single-crystal X-ray analysis has shown that p-tert-butylthiacalix[4]arene (H4L) binds to Zn2+ ion by bridging sulfur atoms in addition to phenolic oxygen atoms to form [Zn4L(H2L)2].
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1999.219