Synthesis and Spectroscopic Characterization of Heteroleptic Europium(III) Double-deckers Containing 2,3-Naphthalocyaninato and Tetra(4-pyridyl)porphyrinato Ligands

Synthesis and Spectroscopic Characterization of Heteroleptic Europium(III) Double-deckers Containing 2,3-Naphthalocyaninato and Tetra(4-pyridyl)porphyrinato Ligands

The first heteroleptic 2,3-naphthalocyaninato and porphyrinato double-decker complexes, namely Eu(Nc)(TPyP) (1) and Eu[Nc’(SC12H25)8](TPyP) (2), were prepared by the base-promoted cyclization of 2,3-dicyanonaphthalenes using Eu(TPyP)(acac) as the template, and were spectroscopically characterized.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 1999-03, Vol.28 (3), p.261-262
Hauptverfasser: Jiang, Jianzhuang, Du, Daming, Choi, Michael T. M, Xie, Jinglei, Ng, Dennis K. P
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The first heteroleptic 2,3-naphthalocyaninato and porphyrinato double-decker complexes, namely Eu(Nc)(TPyP) (1) and Eu[Nc’(SC12H25)8](TPyP) (2), were prepared by the base-promoted cyclization of 2,3-dicyanonaphthalenes using Eu(TPyP)(acac) as the template, and were spectroscopically characterized.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1999.261