Synthesis, Structure, and Reactivities of the [eta]1:[eta]6-[mu]2-Aryl Alkynyl Diruthenium Complex. X-Ray Structure of [Cp(PPh3)2Ru([eta]1

Synthesis, Structure, and Reactivities of the [eta]1:[eta]6-[mu]2-Aryl Alkynyl Diruthenium Complex. X-Ray Structure of [Cp(PPh3)2Ru([eta]1

Preparation of a η1:η6-μ2-aryl alkynyl diruthenium complex [Cp(PPh3)2Ru(η1:η6-μ2-C≡CC6H4Me-p)RuCp*]Cl (2*Cl) [Cp = η5-C5H5, Cp* = η5-C5Me5] and its reactions with electrophile or CO are reported. The structure of 2*PF6 has been determined by X-ray crystallography.

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Veröffentlicht in:Chemistry letters 1999-09, Vol.28 (9), p.865
Hauptverfasser: Matsuzaka, Hiroyuki, Sato, Yoshiyuki, Okimura, Hironobu, Ishii, Tomohiko, Yamashita, Masahiro, Kitagawa, Susumu, Kondo, Mitsuru, Shiro, Moto-o, Yamasaki, Mikio
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Sprache:eng
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Zusammenfassung:Preparation of a η1:η6-μ2-aryl alkynyl diruthenium complex [Cp(PPh3)2Ru(η1:η6-μ2-C≡CC6H4Me-p)RuCp*]Cl (2*Cl) [Cp = η5-C5H5, Cp* = η5-C5Me5] and its reactions with electrophile or CO are reported. The structure of 2*PF6 has been determined by X-ray crystallography.
ISSN:0366-7022
1348-0715