Synthesis of New Paramagnetic Heterodinuclear Complexes with Dithiolene Bridging Ligands, (Ph2C2S2)Fe(Cp'Ru)([mu]-Ph2C2S2)2 (Cp' = [eta]5-C5H4SiMe3(CpS1), [eta]5-C5Me5(Cp)), by Replacement of a Metal Fragment

Synthesis of New Paramagnetic Heterodinuclear Complexes with Dithiolene Bridging Ligands, (Ph2C2S2)Fe(Cp'Ru)([mu]-Ph2C2S2)2 (Cp' = [eta]5-C5H4SiMe3(CpS1), [eta]5-C5Me5(Cp)), by Replacement of a Metal Fragment

Thermal reactions of (Ph2C2S2)4Fe2 with Cp'2Ru2(CO)4 (Cp' = η5-C5H4SiMe3, η5-C5Me5 (Cp*)) gave new paramagnetic heterodinuclear complexes (Ph2C2S2)Fe(Cp'Ru)(μ-Ph2C2S2)2 bridged by two dithiolene ligands.

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Veröffentlicht in:Chemistry letters 1999-10, Vol.28 (10), p.1075
Hauptverfasser: Kuge, Katsuaki, Inomata, Shinji, Tobita, Hiromi, Ogino, Hiroshi
Format: Artikel
Sprache:eng
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Zusammenfassung:Thermal reactions of (Ph2C2S2)4Fe2 with Cp'2Ru2(CO)4 (Cp' = η5-C5H4SiMe3, η5-C5Me5 (Cp*)) gave new paramagnetic heterodinuclear complexes (Ph2C2S2)Fe(Cp'Ru)(μ-Ph2C2S2)2 bridged by two dithiolene ligands.
ISSN:0366-7022
1348-0715