New Bis(salicylaldiminato) Titanium Complexes for Ethylene Polymerization

New bis(salicylaldiminato) titanium complexes were synthesized and investigated as ethylene polymerization catalysts. These complexes, when activated with methylalumoxane, exhibited one of the highest activities displayed by group 4 transition metal complexes having no cyclopentadienyl ligand(s).

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Veröffentlicht in:Chemistry letters 1999-10, Vol.28 (10), p.1065-1066
Hauptverfasser: Matsui, Shigekazu, Tohi, Yasushi, Mitani, Makoto, Saito, Junji, Makio, Haruyuki, Tanaka, Hidetsugu, Nitabaru, Masatoshi, Nakano, Takashi, Fujita, Terunori
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Sprache:eng
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Zusammenfassung:New bis(salicylaldiminato) titanium complexes were synthesized and investigated as ethylene polymerization catalysts. These complexes, when activated with methylalumoxane, exhibited one of the highest activities displayed by group 4 transition metal complexes having no cyclopentadienyl ligand(s).
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1999.1065