Circular Dichroism Spectrophotometric Determination of Metal Ions by Using Optically Resolved Sparingly Soluble fac(S)-[Rh(aet)3](aet = 2-Aminoethanethiolate)
Sparingly soluble neutral fac(S)-[Rh(aet)3] (aet = 2-aminoethanethiolate) was optically resolved completely. The S-bridged complex formation of the optically active isomer of fac(S)-[Rh(aet)3] was utilized for the selective determination of metal ions by using circular dichroism spectra.
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| Veröffentlicht in: | Chemistry letters 1998-08, Vol.27 (8), p.775-776 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Sparingly soluble neutral fac(S)-[Rh(aet)3] (aet = 2-aminoethanethiolate) was optically resolved completely. The S-bridged complex formation of the optically active isomer of fac(S)-[Rh(aet)3] was utilized for the selective determination of metal ions by using circular dichroism spectra. |
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| ISSN: | 0366-7022 1348-0715 |
| DOI: | 10.1246/cl.1998.775 |