Synthesis and Crystal Structure of a New 3D Scaffold-Like Compound [Mn(4,4′-bipy)(N3)2]n

Synthesis and Crystal Structure of a New 3D Scaffold-Like Compound [Mn(4,4′-bipy)(N3)2]n

A new 3D scaffold-like compound [Mn(4,4′-bipy)(N3)2]n has been synthesized and its structure determined by single-crystal X-ray analysis. The molecular structure consists of a three-dimensional network in which Mn2+ are linked by EE bridged azido ligands and 4,4′-bipy ligands. Magnetic measurement i...

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Veröffentlicht in:Chemistry letters 1998-05, Vol.27 (5), p.469-470
Hauptverfasser: Shen, Hao-Yu, Liao, Dai-Zheng, Jiang, Zong-Hui, Yan, Shi-Ping, Sun, Bai-Wan, Wang, Geng-Lin, Yao Xin-Kan, Wang, Hong-Gen
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Sprache:eng
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Zusammenfassung:A new 3D scaffold-like compound [Mn(4,4′-bipy)(N3)2]n has been synthesized and its structure determined by single-crystal X-ray analysis. The molecular structure consists of a three-dimensional network in which Mn2+ are linked by EE bridged azido ligands and 4,4′-bipy ligands. Magnetic measurement indicates that the overall magnetic behavior is weakly antiferromagnetic.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1998.469