Mixed-valence Hexanuclear Cobalt(II, III) Complex Made Up of Two Defective Cubane Cores
A mixed-valence cobalt(II, III) complex, [Co6L2(CH3COO)2(CH3O)6L′]·2CH3OH(H3L=2,6-bis(saliclylideneaminomethyl)-4-methylphenol and H2L′=salicylazine), has been isolated and characterized by X-ray crystallography, which reveals a unique hexanuclear structure consisting of two defective cubane-cores....
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| Veröffentlicht in: | Chemistry letters 1998-05, Vol.27 (5), p.421-422 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A mixed-valence cobalt(II, III) complex, [Co6L2(CH3COO)2(CH3O)6L′]·2CH3OH(H3L=2,6-bis(saliclylideneaminomethyl)-4-methylphenol and H2L′=salicylazine), has been isolated and characterized by X-ray crystallography, which reveals a unique hexanuclear structure consisting of two defective cubane-cores. |
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| ISSN: | 0366-7022 1348-0715 |
| DOI: | 10.1246/cl.1998.421 |