Novel Extended Linear Structure of Decavanadate Anions Linked by Bis(4-Pyridinium) Disulfide (H2dpds), {(H2dpds)2[V10O26(OH)2]·10H2O}n

Novel Extended Linear Structure of Decavanadate Anions Linked by Bis(4-Pyridinium) Disulfide (H2dpds), {(H2dpds)2[V10O26(OH)2]·10H2O}n

New porous coordination polymer, {(H2dpds)2[V10O26(OH)2]·10H2O}n (H2dpds = bis(4-pyridinium) disulfide), was synthesized and structurally characterized. X-ray analysis demonstrates that the decavanadate anions are doubly bridged by H2dpds ligands to provide a one-dimensional structure. This network...

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Veröffentlicht in:Chemistry letters 1999-04, Vol.28 (4), p.291-292
Hauptverfasser: Kondo, Mitsuru, Fujimoto, Kentaro, Okubo, Takashi, Asami, Akiko, Noro, Shin-ichiro, Kitagawa, Susumu, Ishii, Tomohiko, Matsuzaka, Hiroyuki
Format: Artikel
Sprache:eng
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Zusammenfassung:New porous coordination polymer, {(H2dpds)2[V10O26(OH)2]·10H2O}n (H2dpds = bis(4-pyridinium) disulfide), was synthesized and structurally characterized. X-ray analysis demonstrates that the decavanadate anions are doubly bridged by H2dpds ligands to provide a one-dimensional structure. This network affords channeling cavities with dimension of about 2 × 4 Å along the c-axis.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1999.291