Combined Effect of Bulkiness and NH···S Hydrogen Bonding Controls the Formation of Terminal and Bridging Hydrazine Ruthenium(II) Complexes with Thiolate Ligands

Combined Effect of Bulkiness and NH···S Hydrogen Bonding Controls the Formation of Terminal and Bridging Hydrazine Ruthenium(II) Complexes with Thiolate Ligands

The coordinatively unsaturated 16 electron ruthenium-thiolate complexes (η6-C6H6)Ru(S-2,6-C6H3Me2)2 (1) and (η6-C6Me6)Ru(S2C6H4) (2: S2C6H4 = 1,2-benzenedithiolate) react with an excess of hydrazine hydrate to afford a mononuclear η1-hydrazine complex (η6-C6H6)Ru(η1-NH2NH2)(S-2,6-C6H3Me2)2 (3) and a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 1997-06, Vol.26 (6), p.569-570
Hauptverfasser: Mashima, Kazushi, Kaneyoshi, Hiromu, Kaneko, Sei-ichi, Tani, Kazuhide, Nakamura, Akira
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 570
container_issue 6
container_start_page 569
container_title Chemistry letters
container_volume 26
creator Mashima, Kazushi
Kaneyoshi, Hiromu
Kaneko, Sei-ichi
Tani, Kazuhide
Nakamura, Akira
description The coordinatively unsaturated 16 electron ruthenium-thiolate complexes (η6-C6H6)Ru(S-2,6-C6H3Me2)2 (1) and (η6-C6Me6)Ru(S2C6H4) (2: S2C6H4 = 1,2-benzenedithiolate) react with an excess of hydrazine hydrate to afford a mononuclear η1-hydrazine complex (η6-C6H6)Ru(η1-NH2NH2)(S-2,6-C6H3Me2)2 (3) and a dinuclear μ-hydrazine complex [(η6-C6Me6)Ru(S2C6H4)]2(μ-NH2NH2) (4), respectively.
doi_str_mv 10.1246/cl.1997.569
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1460874517</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3135127521</sourcerecordid><originalsourceid>FETCH-LOGICAL-c223t-ce42234032b9789533c0cd27186b890a69db40e0b3e95894d553864daddf66663</originalsourceid><addsrcrecordid>eNptkcFqGzEURUVpoW6aVX9AkE1LGVcaaTTSsjZJbDApNO560EgaW86M5EoaWvd38hHd58uiSbLoou8tHohzD4gLwAeM5rik7Ivq51iIel4x8QrMMKG8QDWuXoMZIowVNSrLt-BdjAeEEBeknIH7pR9a64yGl11nVIK-g4uxv8tPMULpNLxZPfyd9hauTjr4nXFw4Z22bgeX3qXg-wjT3sArHwaZrHeTYmvCYJ3snwyLYPVu4ieB_JPV8PuYI86Ow8f1-lP2DMfe_DYR_rJpD7d763uZDNzYXc7H9-BNJ_tozl_uGfhxdbldrorNt-v18uumUGVJUqEMzZciUrai5qIiRCGlyxpz1nKBJBO6pciglhhRcUF1VRHOqJZadywPOQMXz95j8D9HE1Nz8GPIv4gNpgzxmla4ztTnZ0oFH2MwXXMMdpDh1GDUTC00qm-mFprcQqb5C703g1XZ5ZU16XSQR-n-8f8n-gi3npDZ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1460874517</pqid></control><display><type>article</type><title>Combined Effect of Bulkiness and NH···S Hydrogen Bonding Controls the Formation of Terminal and Bridging Hydrazine Ruthenium(II) Complexes with Thiolate Ligands</title><source>Oxford University Press Journals All Titles (1996-Current)</source><creator>Mashima, Kazushi ; Kaneyoshi, Hiromu ; Kaneko, Sei-ichi ; Tani, Kazuhide ; Nakamura, Akira</creator><creatorcontrib>Mashima, Kazushi ; Kaneyoshi, Hiromu ; Kaneko, Sei-ichi ; Tani, Kazuhide ; Nakamura, Akira</creatorcontrib><description>The coordinatively unsaturated 16 electron ruthenium-thiolate complexes (η6-C6H6)Ru(S-2,6-C6H3Me2)2 (1) and (η6-C6Me6)Ru(S2C6H4) (2: S2C6H4 = 1,2-benzenedithiolate) react with an excess of hydrazine hydrate to afford a mononuclear η1-hydrazine complex (η6-C6H6)Ru(η1-NH2NH2)(S-2,6-C6H3Me2)2 (3) and a dinuclear μ-hydrazine complex [(η6-C6Me6)Ru(S2C6H4)]2(μ-NH2NH2) (4), respectively.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1246/cl.1997.569</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><ispartof>Chemistry letters, 1997-06, Vol.26 (6), p.569-570</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 1997</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c223t-ce42234032b9789533c0cd27186b890a69db40e0b3e95894d553864daddf66663</citedby><cites>FETCH-LOGICAL-c223t-ce42234032b9789533c0cd27186b890a69db40e0b3e95894d553864daddf66663</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Mashima, Kazushi</creatorcontrib><creatorcontrib>Kaneyoshi, Hiromu</creatorcontrib><creatorcontrib>Kaneko, Sei-ichi</creatorcontrib><creatorcontrib>Tani, Kazuhide</creatorcontrib><creatorcontrib>Nakamura, Akira</creatorcontrib><title>Combined Effect of Bulkiness and NH···S Hydrogen Bonding Controls the Formation of Terminal and Bridging Hydrazine Ruthenium(II) Complexes with Thiolate Ligands</title><title>Chemistry letters</title><addtitle>Chemistry Letters</addtitle><description>The coordinatively unsaturated 16 electron ruthenium-thiolate complexes (η6-C6H6)Ru(S-2,6-C6H3Me2)2 (1) and (η6-C6Me6)Ru(S2C6H4) (2: S2C6H4 = 1,2-benzenedithiolate) react with an excess of hydrazine hydrate to afford a mononuclear η1-hydrazine complex (η6-C6H6)Ru(η1-NH2NH2)(S-2,6-C6H3Me2)2 (3) and a dinuclear μ-hydrazine complex [(η6-C6Me6)Ru(S2C6H4)]2(μ-NH2NH2) (4), respectively.</description><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNptkcFqGzEURUVpoW6aVX9AkE1LGVcaaTTSsjZJbDApNO560EgaW86M5EoaWvd38hHd58uiSbLoou8tHohzD4gLwAeM5rik7Ivq51iIel4x8QrMMKG8QDWuXoMZIowVNSrLt-BdjAeEEBeknIH7pR9a64yGl11nVIK-g4uxv8tPMULpNLxZPfyd9hauTjr4nXFw4Z22bgeX3qXg-wjT3sArHwaZrHeTYmvCYJ3snwyLYPVu4ieB_JPV8PuYI86Ow8f1-lP2DMfe_DYR_rJpD7d763uZDNzYXc7H9-BNJ_tozl_uGfhxdbldrorNt-v18uumUGVJUqEMzZciUrai5qIiRCGlyxpz1nKBJBO6pciglhhRcUF1VRHOqJZadywPOQMXz95j8D9HE1Nz8GPIv4gNpgzxmla4ztTnZ0oFH2MwXXMMdpDh1GDUTC00qm-mFprcQqb5C703g1XZ5ZU16XSQR-n-8f8n-gi3npDZ</recordid><startdate>19970601</startdate><enddate>19970601</enddate><creator>Mashima, Kazushi</creator><creator>Kaneyoshi, Hiromu</creator><creator>Kaneko, Sei-ichi</creator><creator>Tani, Kazuhide</creator><creator>Nakamura, Akira</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19970601</creationdate><title>Combined Effect of Bulkiness and NH···S Hydrogen Bonding Controls the Formation of Terminal and Bridging Hydrazine Ruthenium(II) Complexes with Thiolate Ligands</title><author>Mashima, Kazushi ; Kaneyoshi, Hiromu ; Kaneko, Sei-ichi ; Tani, Kazuhide ; Nakamura, Akira</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c223t-ce42234032b9789533c0cd27186b890a69db40e0b3e95894d553864daddf66663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mashima, Kazushi</creatorcontrib><creatorcontrib>Kaneyoshi, Hiromu</creatorcontrib><creatorcontrib>Kaneko, Sei-ichi</creatorcontrib><creatorcontrib>Tani, Kazuhide</creatorcontrib><creatorcontrib>Nakamura, Akira</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mashima, Kazushi</au><au>Kaneyoshi, Hiromu</au><au>Kaneko, Sei-ichi</au><au>Tani, Kazuhide</au><au>Nakamura, Akira</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Combined Effect of Bulkiness and NH···S Hydrogen Bonding Controls the Formation of Terminal and Bridging Hydrazine Ruthenium(II) Complexes with Thiolate Ligands</atitle><jtitle>Chemistry letters</jtitle><addtitle>Chemistry Letters</addtitle><date>1997-06-01</date><risdate>1997</risdate><volume>26</volume><issue>6</issue><spage>569</spage><epage>570</epage><pages>569-570</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>The coordinatively unsaturated 16 electron ruthenium-thiolate complexes (η6-C6H6)Ru(S-2,6-C6H3Me2)2 (1) and (η6-C6Me6)Ru(S2C6H4) (2: S2C6H4 = 1,2-benzenedithiolate) react with an excess of hydrazine hydrate to afford a mononuclear η1-hydrazine complex (η6-C6H6)Ru(η1-NH2NH2)(S-2,6-C6H3Me2)2 (3) and a dinuclear μ-hydrazine complex [(η6-C6Me6)Ru(S2C6H4)]2(μ-NH2NH2) (4), respectively.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.1997.569</doi><tpages>2</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0366-7022
ispartof Chemistry letters, 1997-06, Vol.26 (6), p.569-570
issn 0366-7022
1348-0715
language eng
recordid cdi_proquest_journals_1460874517
source Oxford University Press Journals All Titles (1996-Current)
title Combined Effect of Bulkiness and NH···S Hydrogen Bonding Controls the Formation of Terminal and Bridging Hydrazine Ruthenium(II) Complexes with Thiolate Ligands
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T05%3A45%3A40IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Combined%20Effect%20of%20Bulkiness%20and%20NH%C2%B7%C2%B7%C2%B7S%20Hydrogen%20Bonding%20Controls%20the%20Formation%20of%20Terminal%20and%20Bridging%20Hydrazine%20Ruthenium(II)%20Complexes%20with%20Thiolate%20Ligands&rft.jtitle=Chemistry%20letters&rft.au=Mashima,%20Kazushi&rft.date=1997-06-01&rft.volume=26&rft.issue=6&rft.spage=569&rft.epage=570&rft.pages=569-570&rft.issn=0366-7022&rft.eissn=1348-0715&rft_id=info:doi/10.1246/cl.1997.569&rft_dat=%3Cproquest_cross%3E3135127521%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1460874517&rft_id=info:pmid/&rfr_iscdi=true