Combined Effect of Bulkiness and NH···S Hydrogen Bonding Controls the Formation of Terminal and Bridging Hydrazine Ruthenium(II) Complexes with Thiolate Ligands

Combined Effect of Bulkiness and NH···S Hydrogen Bonding Controls the Formation of Terminal and Bridging Hydrazine Ruthenium(II) Complexes with Thiolate Ligands

The coordinatively unsaturated 16 electron ruthenium-thiolate complexes (η6-C6H6)Ru(S-2,6-C6H3Me2)2 (1) and (η6-C6Me6)Ru(S2C6H4) (2: S2C6H4 = 1,2-benzenedithiolate) react with an excess of hydrazine hydrate to afford a mononuclear η1-hydrazine complex (η6-C6H6)Ru(η1-NH2NH2)(S-2,6-C6H3Me2)2 (3) and a...

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Veröffentlicht in:Chemistry letters 1997-06, Vol.26 (6), p.569-570
Hauptverfasser: Mashima, Kazushi, Kaneyoshi, Hiromu, Kaneko, Sei-ichi, Tani, Kazuhide, Nakamura, Akira
Format: Artikel
Sprache:eng
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Zusammenfassung:The coordinatively unsaturated 16 electron ruthenium-thiolate complexes (η6-C6H6)Ru(S-2,6-C6H3Me2)2 (1) and (η6-C6Me6)Ru(S2C6H4) (2: S2C6H4 = 1,2-benzenedithiolate) react with an excess of hydrazine hydrate to afford a mononuclear η1-hydrazine complex (η6-C6H6)Ru(η1-NH2NH2)(S-2,6-C6H3Me2)2 (3) and a dinuclear μ-hydrazine complex [(η6-C6Me6)Ru(S2C6H4)]2(μ-NH2NH2) (4), respectively.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1997.569