Circular Dichroism of an Aromatic Guest Induced by a Chiral Steroid Cyclophane in Aqueous Solution and Synthetic Bilayer Membrane
A steroid cyclophane, having L-lysine residues interposed between a tetraaza[6.1.6.1]paracyclophane skeleton and four cholate moieties, furnished a chiral binding site for a hydrophobic aromatic guest in a synthetic bilayer membrane as well as in aqueous solution, as evidenced by induced circular di...
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| Veröffentlicht in: | Chemistry letters 1996-09, Vol.25 (9), p.771-772 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A steroid cyclophane, having L-lysine residues interposed between a tetraaza[6.1.6.1]paracyclophane skeleton and four cholate moieties, furnished a chiral binding site for a hydrophobic aromatic guest in a synthetic bilayer membrane as well as in aqueous solution, as evidenced by induced circular dichroism. |
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| ISSN: | 0366-7022 1348-0715 |
| DOI: | 10.1246/cl.1996.771 |