Synthesis and Property of Planar-chiral Cyclopentadienyl-ruthenium Complexes

Synthesis and Property of Planar-chiral Cyclopentadienyl-ruthenium Complexes

The first enantiomerically pure planar-chiral cyclopentadienyl-ruthenium complexes, [CpnRu(benzene)]PF6, were synthesized (CpnH; unsymmetricaly trisubstituted cyclopentadiene), and by a photo reaction with CH3CN converted to [CpnRu(CH3CN)3]PF6, which was transformed into planar-chiral [CpnRu(arene)]...

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Veröffentlicht in:Chemistry letters 1996-08, Vol.25 (8), p.677-678
Hauptverfasser: Komatsuzaki, Nobuko, Uno, Mitsunari, Kikuchi, Hidetoshi, Takahashi, Shigetoshi
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container_issue 8
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container_title Chemistry letters
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creator Komatsuzaki, Nobuko
Uno, Mitsunari
Kikuchi, Hidetoshi
Takahashi, Shigetoshi
description The first enantiomerically pure planar-chiral cyclopentadienyl-ruthenium complexes, [CpnRu(benzene)]PF6, were synthesized (CpnH; unsymmetricaly trisubstituted cyclopentadiene), and by a photo reaction with CH3CN converted to [CpnRu(CH3CN)3]PF6, which was transformed into planar-chiral [CpnRu(arene)]PF6 by a ligand exchange reaction.
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title Synthesis and Property of Planar-chiral Cyclopentadienyl-ruthenium Complexes
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